The official Twitter feed of the Italian Serie A club Napoli tweeted a teaser of the new season on Saturday, which is expected to air on a variety of TV channels in Italy.
The new season will begin on Monday, with the Italian giants facing Napoli at the San Paolo Stadium in a Serie A game on the weekend of October 30.
Napoli are currently second in Serie A with eight points from three games.
Napolitano will take charge of Napoli on October 29.
The team will begin their first season in the top flight on the 25th of September and they will finish the season with a record of six wins from nine matches.
The Italian club has been the most successful in Serie B and is in third place in the standings.
The Serie B champions are currently the top team in the league with a league-best 38 points.
Napoleon is the longest serving player in Serie D, having been in charge since 2010.
The Napoli legend will also be taking over the reins as president of the club, having led the club since 2011.